Anfield test for Boro
Middlesbrough have received an away tie to Liverpool in the Capital One Cup third round.
Boro made it through after defeating Preston North End 3-1 at the Riverside earlier this week.
Elsewhere, MK Dons host League One rivals Bradford City following their respective victories over Manchester United and Leeds United.
Defending champions Manchester City welcome Sheffield Wednesday, Chelsea entertain Bolton Wanderers and Arsenal take on Southampton in other leading ties.
Matches to be played on 23rd-24th September.